文档介绍:IUPAC Nomenclature of Alcohols,
Ethers and Phenols
Naming Alcohols
Naming Phenols
Naming Ethers
Preparation of alcohols,Ethers and
Phenols
Preparation of alcohols
A. Preparation of alcohols by
reduction of pounds
(1) Hydrogenation of aldehydes and
ketones by catalysis of metals
(2) Reduction of pounds
by metal hydrides
B. Preparation of diols
Chapter 9
Alcohols, Ethers and phenols
Preparation of Ethers
A. Ethers by intermolecular dehydration
of alcohols
B. Williamson Synthesis of Ethers
Preparation of phenols
A. Laboratory synthesis
B. Industrial synthesis
Reactions of Alcohols
The sites of reactions of a Alcohol
Acidity and Basicity of Alcohols
Conversion of alcohols to ethers
Oxidation of alcohols
A. Oxidation of primary alcohols
B. Oxidation of secondary alcohols
C. Oxidation of vicinal diols
Reactions of phenols
Acidity of Phenols
Electrophilic aromatic substitutions
Acylation of phenols
Fries rearrangement
Kolbe-Schmitt reaction
Preparation of aryl ethers
Cleavage of aryl ethers by hydrogen
halides
Claisen rearrangement of
allyl aryl ethers
Oxidation of phenols: Quinones
Reactions of Ethers
Acid-catalyzed cleavage of ethers
Preparation of epoxides
of alkenes by reaction
with peroxy acids
B. Conversion of vicinal halodrins
to epoxides
Reactions of Epoxides
A. Base-catalyzed ring opening
B. Acid-catalyzed ring opening
Y
Acetyl halides
酰卤
Esters
酯
Carboxylic acid
anhydrides
酸酐
Amides
酰胺
Carboxylic Carboxylic acid
acid derivatives
羧酸羧酸衍生物
Compounds with O-containing
functional groups
Alcohol Ether Phenol Aldehyde Ketone
醇醚酚醛酮
The interplay of these
compounds is fundamental
anic chemistry and biochemistry
Alcohol Ether Phenol Aldehyde Ketone
醇醚酚醛酮
Compounds that have hydroxyl
group bonded to a saturated,
sp3-C atom-Alcohols.
Compounds