文档介绍：2
石油化工

2009年第 38卷第 3期 PETROCHEM ICAL TECHNOLOGY · 225·
特约述评
H2S分解制氢技术研究进展
白雪峰
(黑龙江省科学院石油化学研究院,黑龙江哈尔滨 150040)
[摘要] H2 S 分解制氢可充分利用石油化工、煤化工及天然气化工等生产过程中产生的 H2 S 废气, 不仅解决环境污染问题, 还可
避免采用 C laus工艺处理 H2 S废气时氢资源的浪费。对 H2 S 分解制氢的工艺过程和技术进展进行了综述,包括高温热分解法、催
化热分解法、超绝热分解法、电化学法、化学法、等离子体法、光化学与光催化法等,分析和阐述了各工艺的特点和优缺点。光催化
H2 S 分解制氢工艺条件缓和,能耗低,可利用丰富、廉价的太阳能资源,是一种有开发前景的工艺路线。
[关键词] 硫化氢; 制氢; 分解; 光催化
[文章编号] 1000 - 8144 (2009) 03 - 0225 - 09 [中图分类号] TQ 116. 29 [文献标识码] A
Progress in Research of H 2 S D ecom position for Hydrogen Production
B a i Xuefeng
( Institute of Petrochem istry, Heilongjiang A cadem y of Sciences, Harbin Heilongjiang 150040, China)
[ Abstract] The H2 S position p rocess for hydrogen p roduction takes full advantage of industrial
w aste H2 S p roduced in petroleum , coal and natural gas industry. It not only can solve environm ental
p roblem s, but also avoid the w aste of hydrogen resource resulting from C laus p rocesse. The m ain
technologies for H2 S position for hydrogen p roduction, including high tem perature therm olysis,
catalytic therm olysis, superadiabatic therm olysis, electrochem ical, chem ical, p lasm a chem ical,
photochem ical & photocatalytic positions, etc. , w ere introduced. Their characteristics,
advantages & disadvantages w ere stated and analyzed. Technology of hydrogen p roduction by
photocatalytic position