北京市2017届高三化学总复习指导第四部分常见有机物及其应用配套练习题答案.doc

文档介绍：:..一、 、 简答题16.(1)CI0HI2O2竣基-£ch-cihi(2) xm17.(I)乙醇(2)CH3COOH+C2H5OHfll3^ffiCH3COOC2H5+H2OCH2COOC2H5(3)C9H10O3水解反应(4)3Cj—COOH I)-以勺Q-fHT:O(川OH <>H (任意答对一个即可)18.(1)碳碳双键、醛基(2)CH3CH2CHOCH2=C-COOH+HOCH2CH2OH口葩酗ch2=c-cooch2ch2oh+h2o(3)ICH? CH3(4)ab19.(1)竣基、轻基(2)①②③④no(3)(4)448(5)U2OCIICOCKH:CH:20.(1)(2)①(任写出一种即可)21-(1)(2)bd(3)竣基IK)FUCH;CH4)HCH2coonClhHUIH)CH:CH:仁OOCIbCHi(4)Ci2H1()O5 3②④ooo oooIIIIII IIIIIICH3-C-C-C-O-CH3+NaOH^MCH3-C-C-C-ONa+CH3OH②CH,③4(5)C8H6O413—H+3NaOILA>H=CH—COOHXTONa-NaO—(:—H+2H2O(2) 9(3) 保护酚疑基,使之不被氧化(4)(:()(川CH=(:H2H!kCOONa:H2CH2OH|H|COONa23.(1)CH3CH(OH)COOH/K?H2=CHCOOCH5(H2CH2BrCOOHCH2(:H2()H浓h$0,COOH空Hch?t严COOCH,NM川/1以)