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Organic Reaction Mechanisms
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Organic Reaction Mechanisms
A Step by Step Approach
Second Edition
MICHAEL EDENBOROUGH
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UK Taylor & Francis Ltd, 1 Gunpowder Square, London EC4A 3DE
USA Taylor & Francis Inc., 325 Chestnut Street, 8th Floor, Philadelphia, PA 19106
This edition published in the Taylor & Francis e-Library, 2004.
© Michael Edenborough 1999
All rights reserved. No part of this publication may be reproduced, stored in a
retrieval system, or transmitted, in any form or by any means, electronic, electrostatic,
ic tape, mechanical, photocopying, recording or otherwise, without the prior
permission of the copyright owner. The author has asserted his right to be identified as
the author of this work pursuant to sections 77 and 78 of the Copyright, Designs and
Patents Act 1988.
British Library Cataloguing in Publication Data
A catalogue record for this book is available from the British Library.
ISBN 0-203-21247-9 Master e-book ISBN
ISBN 0-203-29087-9 (OEB Format)
ISBN 0-7484-06417 (paper)
Library of Congress Cataloguing in Publication data are available
Cover design by Amanda Barragry Design
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Contents
Preface to the First Edition xi
Preface to the Second Edition xiii
1
Part I: Basic Principles
1 Introduction 3
The aims of this book 3
What anic chemistry? 4
synthesis 5
mechanisms 6
Two examples 6
The structure of this book 11
2 Electron Counting 13
Introduction 13
Atoms 13
Uncharged molecules 19
Molecules with whole charges 22
S