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有机太阳能电池.pdf

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有机太阳能电池.pdf

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文档介绍:Self-Assembled Monolayer Immobilized Gold Nanoparticles for Plasmonic E ?ects in Small anic Photovoltaic Ming-Chung Chen, ?Yi-Ling Yang, ?Shin-Wen Chen, ?Jia-Han Li, ?Muluken Aklilu, ?and Yian Tai * , ??Department of Chemical Engineering, National Taiwan University of Science and Technology, 43 Keelung Road , Taipei-10607, Taiwan ?Department of Engineering Science and Ocean Engineering, National Taiwan University, No. 1, Sec. 4, Roosevelt Rd, Taipei-10617, Taiwan * SSupporting Information ABSTRACT: The aim of this study was to investigate the e ?ect of gold nanoparticle (Au NP)-induced surface plasmons on the performance anic photovoltaics (OPVs) that consist of copper phthalocyanine and fullerene as the active materials. The photon absorption can be enhanced by immobilization of surfactant-stabilized Au NPs on a self-assembled monolayer- modi ?ed indium tin oxide (ITO) electrode, and thus, the photocurrent as well as the power conversion e ?ciency (PCE) of these OPVs can be improved. Varying the density of the immobilized Au NPs in the devices provided no signi ?cant variation in the charge mobility but it did enhance the photocurrent. In addition, device simulation results demonstrated that the improvement in photocurrent was due to the enhancement of light absorption and the increase in charge separation, which was facilitated by the Au NPs. Overall, we attributed the i