文档介绍：University of Science and Technology Liaoning
毕业设计(论文)
课题名称 含N，O原子的铜配合物的的合成
院 系 化学工程学院
专业班级 应用化学
学生姓名
指导教师
二零一五 年 六 月
含N，O原子的铜配合物的的合成
摘 要
席夫碱配体在配位化学中被广泛应用的一种配位体，它们的配合物在很多重要的催化反应中得到应用，从不对称的环氧化作用，路易斯酸辅助的有机转化，环氧化物的开环，到各种聚合反应，它们还广泛用作模型化合物来做金属酶活性位点的研究及其他方面的应用。基于文献的基础上，考虑到经济和环境的原因，设计合成双希夫碱及其配合物，采用三组分一锅的微量反应，用三乙***作催化剂，在无溶剂室温条件下用水杨醛和芳香醛合成希夫碱。实验继续利用合成的配体中的N,O配位原子与铜离子进行络合，得到铜配合物。此合成方法具有很多优点：减少污染，成本低、过程和处理简单。
关键词：铜配合物；席夫碱；N,O配位原子；催化剂；合成
Synthesis of copper complexes Containing
N, O atoms
Abstract
A ligand Schiff base ligand in coordination chemistry has been widely used, and their complexes has been applied in many important catalytic reactions, from asymmetric epoxidation, Lewis acid assisted organic transformations, epoxide ring-opening, to the various polymerization reaction, they are also widely used as a model compound to do the research and application of other aspects of metalloproteinase activity sites. Multi-component reaction in the absence of solvent or solid phase occurs been reported reported. On the basis of literature, taking into account economic and environmental reasons, the production of synthesis double Schiff base and its complex design, using a three-component trace pot reaction in the absence of solvent at room temperature with salicylaldehyde,aromatic aldehydes synthesis and triethylamine as a catalyst of Schiff base. Experiments continue to use synthetic ligands N, O ligand atoms and copper ions complexed to obtain a copper complex. This synthesis method has many advantages: reducing pollution, low cost, simple process and handling.
Key Words : Schiff base;Copper complexes；N, O ligand atoms; Catalyst;Synthesis
目 录
摘 要 I
Abstract II
目 录 III
1文献综述 1
席夫碱的应用 1
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