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A. 介词假如位于作为其宾语的关系代词之前时，只能用whom、 which不能用who或that.
(1). The girl about whom they were talking is our monitor.
(2). The book in which there are many interesting things was written by Li Ming.
B. 部分短语动词中的介词不行与动词拆开，在定语从句中其介词不行前置，只能放在其动词之后。
Is this the book which she is looking for?
The old man who/whom they are waiting for is Professor Li.
The child who/whom she is looking after is Wang Ping’s son.
C. 指物时，下列状况下只能用that ，不宜用which。
(1)先行词为不定代词，如All、much、anything、everything、nothing、something、none、the one等。
We are willing to do anything that is good to the people.
I have told them all (that) I know.
All that can be done has been done.
(2)先行词是序数词或被序数词、修饰时。
The first book that I read last night was an English novel.
(3)先行词是形容词最高级或被最高级修饰时。
This is one of the most interesting films that I have ever seen.
This is the best that can be done now.
(4)假如有两个或两个以上分别表示人和物的先行词时(先行词既有人又有物)，定语从句的关系代词用which和who都不合适，只能用that。
We know nothing about the doctors and the hospitals that you are talking about.
There are sheep and men that can be seen on the hill.
(5)假如先行词被the only、the very、the last、the same、any、 few 、little、no、 all 、one of、 just修饰时。
This is the only book that can be lent to you.
(6)当主句是以which开头的特别问句时，关系代词只用that。
Which is the dictionary that he used yesterday ?
，下列状况下只能用which，不宜用that。
(1)关系代词放在介词之后
This is the factory in which we once worked.
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