文档介绍：3
2
2
2 2 2
3 3
2
2
2
2
2
2
3 3
第 21 卷第 9 期化学进展 Vol. 21 No. 9
2009 年 9 月 PROGRESS IN CHEMISTRY Sep. , 2009
金属有机骨架化合物( MOFs) 作为储氢材料
的研究进展
3
3 3 2 贾超原鲜霞马紫峰
(上海交通大学化学工程系上海 200240)
摘要氢的储存对于 21 世纪氢经济时代的发展至关重要。金属有机骨架化合物(MOFs) 因具有纯度
高、结晶度高、成本低、能够大批量生产和结构可控等优点,在气体存储尤其是氢的存储方面展示出广阔的应
用前景。本文详细综述了近年来 MOFs 类化合物(MOF 5 、IRMOFs 和 MMOMs) 作为储氢材料的研究进展,介
绍了各种用于改善 MOFs 材料储氢性能的结构改性方法,总结了 MOFs 储氢材料在理论模拟计算方面的工
作,并指出了 MOFs 储氢材料目前存在的不足和发展方向。
关键词金属有机骨架化合物储氢材料中心金属离子有机联结体
中图分类号: TK91 ; O627 文献标识码: A 文章编号: 1005 281X(2009) 09 1954 09
anic Frameworks ( MOFs) as Hydrogen Storage Materials
Jia Chao Yuan Xianxia Ma Zifeng
(Department of Chemical Engineering , Shanghai Jiao Tong University , Shanghai 200240 , China)
Abstract Hydrogen storage technology is of great importance for hydrogen economy in the 21st century. With the
merits of high purity , high crystallization , low cost , large scale productive capability and structure controllable
characteristics , anic frameworks (MOFs) have been proved to be very promising in the field of gas storage
especially hydrogen storage. In this paper , the research progress of MOFs , including MOF 5 , IRMOFs and MMOMs , as
hydrogen storage materials in recent years is detailedly reviewed , the structure modifying technologies for improving
hydrogen storage capability of MOFs are systematically introduced , the research