文档介绍：Nitrosation Reactions and the
Chemistry of Nitric Oxide
El sevier, 2004
Author: . Williams
ISBN: 978-0-444-51721-0
by kmno4
CONTENTS
INTRODUCTION
1. Reagents effecting nitrosation
. Nitrous acid
. Acid catalysed pathways
. Reaction via dinitrogen trioxide N203
. Nucleophile catalysed pathways
. Nitrosyl halides HalNO
. Nitrosonium salts NO'X-
. Alkyl nitrites RON0
. Reactions in aqueous acid solution
. Reactions in aqueous basic solution
. Reactions in non-aqueous solvents
. N-Nitrososulfonamides RS02N(NO)R1
. Nitrogen oxides
. Nitric oxide NO
. Nitrogen dioxide NO2
. Miscellaneous reagents
2. Nitrosation at nitrogen centres
. Primary aromatic amines
. Primary aliphatic amines
v1 Contents
. Secondary amines
. Tertiary amines
. Amides and pounds
. Other nitrogen-pounds
3. The reactions of N-nitrosamines and pounds
. Rearrangement of aromatic N-nitrosamines Ar(R)NNO
(the Fischer-Hepp rearrangement)
. Denitrosation of nitrosamines R(R1)NNO
. Denitrosation of nitrosamides RCON(N0)R'
. Denitrosation of nitrososulfonamides ArS02N(NO)R
. Carcinogenic properties of N-pounds
4. Aliphatic and alicyclic C-nitrosation
. Nitrosation of ketones
. Nitrosation of other pounds
. Nitrosation of nitroalkanes
. Nitrosation of carbanions
. Addition to alkenes
5. Aromatic C-nitrosation
. Products of the reactions
. Reaction mechanisms
Nitrous acid-catalysed nitration reactions
6. O-Nitrosation
. Nitrosation of alcohols
. Nitrosation of hydrogen peroxide
. Nitrosation of ascorbic acid
. Other O-nitrosation reactions
7. S-Nitrosation
. Nitrosation of thiols
. Nitrosation of thiocarbonyls
. Nitr