文档介绍：Adv Polym Sci (2006) 194: 1–49
DOI
© Springer-Verlag Berlin Heidelberg 2005
Published online: 10 November 2005
Synthesis of Phenol Polymers Using Peroxidases
Matthias Reihmann · Helmut Ritter (u)
Institute anic and Macromolecular Chemistry II,
Heinrich-Heine University of Düsseldorf, Gebäude , Ebene 00,
Universitätsstraße 1, 40225 Düsseldorf, Germany
H.******@uni-
1Introduction.................................. 2
anicReactions........ 2
ThePotentialofEnzymesinPolymerChemistry.............. 3
2 Polymerization of Phenols Using Peroxidases ................ 4
Definitions................................... 4
ThePrincipleofthePeroxide-CatalyzedPolymerization.......... 5
MechanismofthePeroxidaseCatalysis.................... 5
............................. 5
................ 7
..................... 10
MechanismofPhenolPolymerFormation.................. 13
position..................... 14
3 Polymerization of Phenols Using Horseradish Peroxidase ......... 18
UnsubstitutedPhenol............................. 18
p-SubstitutedPhenols............................. 20
m-SubstitutedPhenols............................. 32
o-SubstitutedPhenols,Bisphenols,andotherPhenols........... 36
4 Polymerization of Phenols Using Other Peroxidases ............ 39
5 Polymerization of Phenols Using plexes ............ 41
6Outlook..................................... 44
References ....................................... 45
Abstract This chapter deals with the peroxidase-catalyzed polymerization of phenol and
its derivatives. Such a polymerization needs an oxidation reagent, normally hydrogen
peroxide. Since this type of polymerization is believed to be a potential environmen-
tally friendly alternative process for the production of phenol–formaldehyde resins, it has
been investigated thoroughly by many research groups. Typical re