文档介绍：MichaelAdditionPolymerizationDaHuang2011/10/23ContentIntroductionofMichaelAdditionReactionsMichaelAdditionPolymerizationsLinearstepgrowthMichaeladditionpolymerizationsLinearchaingrowthMichaeladditionpolymerizationsApplicationsofMichaeladditionpolymerizationsMichaelAdditionReactionsDefinition:thebase-catalyzedadditionofanucleophilesuchasanenolate(Michaeldonor)toanactivatedα,β-unsaturatedcarbonyl-pound(eptor).Classification:(杂原子):-Michaelreactionmechanisticscheme:./(2006)487–531HeteroatomicdonorsintheMichaelreactionHeteroatomicdonors:nucleophilesinvolvingN,S,O,-Michaelreaction(amines)-MichaelreactionReactivity:secondaryamines>./(2006)487–531LinearstepgrowthMichaeladditionpolymerizationsSynthesisofPoly(aminoester):hain-./(2006)487–531