文档介绍：Heterogeneous Catalysis anic
Chemistry
Elsevier, 2000
Author(s): Gerard V. Smith and Ferenc Notheisz
ISBN: 978-0-12-651645-6
Preface, Pages xiii-xv
Chapter 1 - Introduction to Catalysis, Pages 1-28
Chapter 2 - Hydrogenations, Pages 29-96
Chapter 3 - Enantioselective Hydrogenations, Pages 97-117
Chapter 4 - Hydrogenolysis, Pages 119-218
Chapter 5 - Bond Breaking Reactions, Pages 219-227
Chapter 6 - Oxidations, Pages 229-246
Chapter 7 - Immobilized Homogeneous Catalysts, Pages 247-289
Appendix, Pages 291-293
Author Index, Pages 295-328
Subject Index, Pages 329-346
3040 | FM Page xiii Thursday, April 15, 1999 5:46 PM
PREFACE
The primary aim of this book is to help the anic chemist with
heterogeneous catalytic methods for making and breaking bonds. This book
has two intentions. First, it is intended to serve the graduate students in
organic chemistry who need to round out their education and learn about het-
erogeneous catalysis and the mechanisms anic reactions on surfaces.
Second, it is intended to aid the anic chemists who have prepared
the pound that will greatly improve the position of pany
but who have just been informed by their supervisors that they must make
their synthetic steps into heterogeneous catalytic steps.
The need to demystify anic reaction mechanisms is vital.
In no other field anic chemistry are the reactions clouded with folklore.
Nowhere is there a greater need to clarify a field that is ing out
of its empirical age and into its scientific age. But barriers exist. One barrier is
the startling lack of any requirements by many journal editors to publish char-
acterization information about the catalysts used in synthetic preparations.
This need is ignored in spite of well-documented facts that the structure of the
catalyst and its preparation and history influence its activity and selectivity.
Not requiring such information propagates the idea that