文档介绍：Electrochemical Reactions and
Mechanisms anic Chemistry
Elsevier, 2000
Author : James Grimshaw
ISBN: 978-0-444-72007-8
Preface, Pages vii-viii
Chapter 1 - Electrochemical Oxidation and Reduction pounds,
Pages 1-26
Chapter 2 - Oxidation of Alkanes, Haloalkanes and Alkenes, Pages 27-53
Chapter 3 - Reduction of Alkenes and Conjugated Alkenes, Pages 54-88
Chapter 4 - Reductive Bond Cleavage Processes-I, Pages 89-157
Chapter 5 - Reductive Bond Cleavage Processes-II, Pages 158-186
Chapter 6 - Oxidation of Aromatic Rings, Pages 187-238
Chapter 7 - Reduction of Aromatic Rings, Pages 239-260
Chapter 8 - Oxidation of Alcohols, Amines and Amides, Pages 261-299
Chapter 9 - Oxidation of Ketones, Aldehydes, and Carboxylic Acids, Pages 300-329
Chapter 10 - Reduction of pounds, Carboxylic Acids and Their
Derivatives, Pages 330-370
Chapter 11 - Reduction of Nitro, Nitroso, Azo and Azoxy Groups, Pages 371-396
Index, Pages 397-401
by kmno4
PREFACE
This book is concerned with reactions carried out at an elects'ode on a prepara-
tive scale. The impact anic electrochemistry on anic chemistry
has a long history beginning with the Kolbe reaction, which is still in the repertoire
in first year teaching. In the early 1900's electrochemical methods for the oxidative
or reductive transformation of functional groups were actively pursued.. They offer
the advantage of having no spent oxidant or reductant for disposal. However elec-
trochernicat processes fell out of favour in the face of conventional chemical reac-
tions because the e from electrochemistry was often far from predictable.
Now that tlre mechanisms of these processes are generally well understood, many
of the former pitfalls can be avoided.
Electrochemical processes use the electron as a reagent and so avoid a chemical
oxidant or reductant, "It~e environmental impact of electrochemistry needs to be
assessed