文档介绍：致谢
首先向我的导师殷锦捷教授致以衷心的感谢。殷锦捷教授严谨的治学态度、深邃的学
术思想、敏锐的洞察力、活跃的科研思维、精益求精的科研精神和对我的严格要求使我深
受教益。本论文的实验及论文写作都是在殷老师的悉心指导下完成的。无论在论文选材、
实验阶段,还是后期的写作无不凝聚着老师心血和汗水。在此向殷老师致以衷心的谢意!
我的实验工作能够顺利进行,与周围老师和同学的帮助是分不开的。在此还要对实验
室的各位老师及同学赵志超、师弟周华利,本科生林莉、张珊珊、盖胜家等,及其他给予
我帮助的师长和同学表示衷心感谢!
同时,我能顺利完成学业也离不开母校的支持和培育。毕业将至,祝愿母校更加进步,
昌盛。
再一次感谢所有为本文付出辛勤劳动的人们!
限于本人水平和实验条件有限,文中难免有不足之处,望各位老师给予纠正。

戴英华

摘要
本文分别采用异氰酸酯(MDI)、聚乙二醇(PEG)和聚乙烯醇(PVA)对酚醛树脂
进行单一增韧和两两复合增韧,再以包覆聚磷酸铵(APP)/三聚氰胺(MEL)/季戊四醇
(PER)协效阻燃及和包覆三聚氰胺聚磷酸盐(MPP)为阻燃剂,从而研制出新型阻燃改
性酚醛泡沫塑料。
本文对改性的酚醛泡沫进行了红外测试(IR),扫描电镜(SEM)分析、冲击强度测
试、拉伸强度测试、吸水率、表观密度以及粉化率测试。结果表明:复合增韧较单一增韧
酚醛泡沫的效果好,冲击强度较纯酚醛泡沫增加了 ,较单一改性增加了
kJ/m2,拉伸强度也提高了 ;阻燃剂的引入使酚醛泡沫塑料具备了更好的阻燃性
能和热稳定性能,燃烧时间下降到 10s,达到了难燃标准。本文列出了此种增韧阻燃酚醛
泡沫塑料的最佳配比。

关键词:酚醛树脂;泡沫塑料;单一增韧;复合增韧;阻燃
- I -
Abstract
The paper modifies phenolic resin with the polyurethane (MDI), PEG, PVA by single
toughing and between posite toughing way, and takes gable ammonium polyphosphate
(APP) / melamine (MEL)/ pentaerythritol (PER) and gable melamine gathers phosphate (MPP)
as the coordinated fire-retardant. Thus it prepares new type flame-retardant phenolic foam.
This article carries on the infrared test (IR), SEM test, iMPact strength test, tensile strength
test water absorption, apparent density and chalking rate test to the toughening modification
phenolic foam. The result indicates that, posite toughing phenolic foam has better
mechanics performance than single toughing phenolic foam, the increased impact strength is
and , compared with pure and single modification, and tensile strength
also increases ; the phenolic foam has better flame retardancy and thermal stability as
the introduction of fire retardant. Burning time decreases to 10s, reaches the flame retardant
standards. This article lists the best allocated proportion.

Key Words:phenolic resin;foam;single posite toughing;flame
ret