文档介绍：2005 年第 63 卷化学学报 Vol. 63, 2005 第 21 期, 2013 ~2016 ACTA CHIMICA SINICA No. 21, 2013 ~ 2016 * E-mail: ******@henu. edu. cn; Tel & Fax: + 86-378-2867282. Received January 7, 2005; revised Ju ly 1, 2005; accepted August 2, 2005. 国家自然科学基金(Nos. 20371015, 90306010) 和“973”前期专项(No. 02700) 资助项目. ·研究简报· 溶胶- 凝胶模板法制备钛酸钡纳米管刘兵张兴堂王洪哲王晓娟李蕴才黄亚彬杜祖亮* ( 河南大学特种功能材料重点实验室开封 475001) 摘要采用氢氧化钡和钛酸四丁酯为前驱体, 溶胶-凝胶结合模板法制备了钛酸钡纳米管, 通过 SEM, TEM, XPS 和 XRD 等表征分析, 钛酸钡纳米管直径 100 nm, 钛酸钡为立方相结构, 晶胞参数 a = ?. 关键词钛酸钡; 纳米管; 溶胶- 凝胶; 模板法 Sol-gel Template Synthesis and Characterization of Barium Titanate Nanotubes LIU, Bing ZHANG, Xing-Tang WANG, Hong-Zhe WANG, Xiao-Juan LI, Yun-Cai HUANG, Ya-Bin DU, Zu-Liang * ( Key Laboratory for Special Functional Materials , Henan University , Kaifeng 475001 ) Abstract The highly ordered barium titanate nanotubes have been fabricated by bination of sol-gel and template methods. Analysis of TEM, SEM, XPS and XRD shows that the barium titanate nanotube is uniform and its diameter is about 100 nm. The barium titanate nanotubes are cubic phase and the parameter of crystal cell is ?. Keywords barium titanate; nanotube; sol-gel; template 钙钛矿结构的钛酸钡由于存在自发极化现象而表现出独特的电学、磁学、光学特性, 诸如: 压电效应、电致伸缩、巨磁电阻效应、热释电现象、较大的非线性光学系数和介电常数, 因而倍受关注, 可用于压电响应扫描探针显微镜、红外线热像仪、计算机存储元件、非线性光学器件、电容器、超声波发生器等. 长期以来人们对钛酸钡纳米颗粒[1,2] 和薄膜[3,4] 的制备和结构性能