文档介绍:ANALYTICAL
ELECTROCHEMISTRY
SECOND EDITION
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ANALYTICAL
ELECTROCHEMISTRY
Second Edition
JOSEPH WANG
WILEY-VCH
A JOHN WILEY & SONS, INC., PUBLICATION
This book is printed on acid-free paper, (ro)
Copyright © 2000 by Wiley-VCH. All rights reserved.
Published simultaneously in Canada.
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Library of Congress Cataloging-in-Pubtication Data:
Wang, Joseph, 1948
Analytical electrochemistry / Joseph Wang.— 2nd ed.
p. cm.
Includes index.
ISBN 0471-28272-3 (Cloth : alk. paper)
1. Electrochemical analysis. I. Title.
2000
543'.0871—<lc21 99-089637
Printed in the United States of America.
10 9876543
Dedicated to the memory of my parents, Elka and Moshe Wang
CONTENTS
PREFACE xi
ABBREVIATIONS AND SYMBOLS xiii
1 FUNDAMENTAL CONCEPTS 1
1-1 Why Electroanalysis? / 1
1-2 Faradaic Processes / 3
1- Mass Transport-Controlled Reactions / 4
1- Potential Step Experiment / 7
1- Potential-Sweep Experiments / 8
1- Reactions Controlled by the Rate of Electron Transfer / 11
1- plex Theory / 16
1-3 The Electrical Double Layer / 18
1-4 Electrocapillary Effect / 22
Supplementary Reading / 25
References