文档介绍：西安工业大学北方信息工程学院本科毕业设计( 论文) 题目: POSS 杂化材料的制备及性能研究系(部) 机电信息系专业: 高分子材料与工程班级: B060211 学生: 吴勤学号: B060 21116 指导教师: 侯永刚 2010 年 06月 i POSS 杂化材料的制备及性能研究摘要 POSS 杂化材料是近年来迅速发展的一类新型材料,受到了众多研究工作者的广泛关注。本文以水和乙醇作为溶剂,以四乙基氢氧化铵作催化剂,由苯基三乙氧基硅烷与二乙烯三氨基丙基***二乙氧基硅烷通过共水解得到含氨基有机硅杂化材料,同时考察了时间、单体比例、催化剂用量、溶剂等 4 种因素对所制备产物产率的影响,采用反滴定法测定了产物的氨基含量,利用红外光谱、热重分析法初步表征了产物结构和热性能。结果表明,当催化剂为 、水 80mL 、乙醇 20mL 、室温( 20℃)时为制备的最佳条件,产物在 700 ℃热残留率约为 72% 。关键词: 倍半硅氧烷;杂化材料;水解共缩合 ii POSS heterozygous material preparation and performance Abstract In recent years have development a new materials was POSS hybrid ,more and more reserchers this paper as water 、 ethanol solvent , phenyltriethoxysilane (PTES) and hydrolysis anic silicon hybrid materials, also of temperature, monomer ratio, amount of catalyst and solvent prepared four kinds of factors influence the yield, determined by reverse titration of amino content of the product, using the FTIR and TG analysis preliminary characterization the product structure and thermal a result of, Tetraethyl ammonium hydroxide (Et4NOH) , water 80mL, ethanol 20mL, temperature (20 ℃) when the best conditions for the preparation of the product at700 ℃ thermal residual rate of about 72%. Keywords : Polyhedral oligomeric silasesquioxanes(POSS) ; Hybridmaterials ; Hydrolytic condensation iii 目录摘要.................................................................................................................................................................... I ABSTRACT ...................................................................................................................................................... II 1 绪论................................................................................................................................................................ 1 概述..................................................................................................................... 1 PO