文档介绍：Phosphorus-31 NMR Spectroscopy
Olaf Kühl
Phosphorus-31 NMR
Spectroscopy
A Concise Introduction for the Synthetic
Organic anometallic Chemist
123
Dr. Olaf Kühl
Universität Greifswald
Institut für Chemie und
Biochemie
Soldtmannstr. 23
17489 Greifswald
Germany
Email, personal: dockuhl@
ISBN: 978-3-540-79117-1 e-ISBN: 978-3-540-79118-8
Library of Congress Control Number: 2008932569
© 2008 Springer-Verlag Berlin Heidelberg
This work is subject to copyright. All rights are reserved, whether the whole or part of the material is
concerned, specifi cally the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting,
reproduction on microfi lm or in any other way, and storage in data banks. Duplication of this publication
or parts thereof is permitted only under the provisions of the German Copyright Law of September 9,
1965, in its current version, and permission for use must always be obtained from Springer. Violations are
liable to prosecution under the German Copyright Law.
The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply,
even in the absence of a specifi c statement, that such names are exempt from the relevant protective laws
and regulations and therefore free for general use.
Cover design: Künkel Lopka GmbH
Printed on acid-free paper
9 8 7 6 5 4 3 2 1
Preface
Nuclear ic Resonance is a powerful tool, especially for the identification of
hitherto pounds. 1H- and 13C-NMR spectroscopy is known
and applied by virtually every synthetically anic Chemist. Conse-
quently, the factors governing the differences in chemical shift values, based on
chemical environment, bonding, temperature, solvent, pH, etc., are well understood,
and specialty methods developed for almost every conceivable structural challenge.
Proton and carbon NMR spectroscopy is part of most bachelors degree courses,
with advanced methods integrated into masters degree and oth