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蒎烯电化学氧化合成蒎烷二醇的可行性研究.doc

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蒎烯电化学氧化合成蒎烷二醇的可行性研究.doc

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文档介绍:-蒎烯电化学氧化合成蒎烷二醇的可行性研究
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浙江工商大学食品、生物与环境工程学院本科毕业论文〔设计〕
a-蒎烯电化学氧化合成蒎烷二醇的可行性研究
题目和摘要,三号,黑体,居中,单倍行距
摘要
小四号,宋体,行距固定值:20镑
本论文提出1S,2S,3R,5S-(+)-2,3-蒎烷二醇是一种重要的药品,其市场需求量在逐年增加,价格也很高。本实验在高锰酸钾氧化a-蒎烯制。本研究结果为蒎烷二醇的合成开辟了一条绿色技术途径〔≥400-500字〕。
关键词:化学氧化;电化学合成;1S,2S,3R,5S-(+)-2,3-蒎烷二醇;钛涂钌铱电极
页边距:、、、、装订线1厘米.
小四号,宋体,词间用分号隔开
小四号,黑体,顶格
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浙江工商大学食品、生物与环境工程学院本科毕业论文〔设计〕
Preliminary study on synthesis of 1s,2s,3r,5s-(+)-pinanediol by electrochemical oxidation process
题目和摘要;三号,Times New Roman,加粗,居中,单倍行距
Abstract
小四号,Times New Roman行距固定值:20镑
A procedure is 1S,2S,3R,5S-(+)-2,3-Pinanediol is significant for humans as a kind of anticancer medicine, of which the demand and price are soaring year by year. On the basis of the chemical synthesis method using potassium permanganate as oxidant, the synthesis of 1S,2S,3R,5S-(+)-2,3-pinanediol by electrochemical oxidation was also explored. It constitutes a electrochemistry system, with 1S-(+)-α-pinene as raw material, tert-butyl alcohol as cosolvent, sodium sulfate as supporting electrolyte, and with ruthenium coated titanium as anode, stainless steel net as cathode. Seeing about the affect of pH, voltage, electrolysis time and whether or not to add membrane to the yield producing 1S,2S,3R, 5S-(+)-2,3-pinanediol. The results showed that the electrochemical synthesis pinanediol is feasible. And at the state of neutral electrolyte without membrane, voltage 12v, reaction time 10h, it could obtain the highest yeild.
Keywords:chemistry oxidation;electrochemical organic synthesis;1S,2S,3R,5S- (+)-2,3- Pinanediol;ruthenium coated ti