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CB644-FM CB644-Petlyuk-v1 June 15, 2004 4:28
Distillation Theory and Its
Application to Optimal Design
of Separation Units
F. B. Petlyuk
v
Cambridge, New York, Melbourne, Madrid, Cape Town, Singapore, São Paulo
Cambridge University Press
The Edinburgh Building, Cambridge , UK
Published in the United States of America by Cambridge University Press, New York
Information on this title: 0521820929
© F. B. Petlyuk 2004
This publication is in copyright. Subject to statutory exception and to the provision of
relevant collective licensing agreements, no reproduction of any part may take place
without the written permission of Cambridge University Press.
First published in print format 2004
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P1: FCH/FFX P2: FCH/FFX QC: FCH/FFX T1: FCH
CB644-FM CB644-Petlyuk-v1 June 15, 2004 4:28
Contents
Preface page xiii
Acknowledgments xvii
Nomenclature xix
1. Phase Equilibrium and Its Geometric Presentation 1
Introduction 1
Concentration Space 1
Phase Equilibrium of Binary Mixtures 3
Phase Diagrams of ponent Mixtures 5
Residue Curve Bundles of ponent Mixtures 8
Matrix Description of the ponent Mixture Residue
Curve Structure 10
Lines, Surfaces, and Hypersurfaces Ki = Kj 12
Liquid–Liquid–Vapor Phase Diagrams 15
Conclusion 17
Questions 18
Exercises with Software 18
References 18
2. Basic Concepts of Distillation 20
Purpose and Process Essence of Distillation 20
. Description of Distillation Process 21