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第 29卷第 3期南京工业大学学报 Vol. 29 No. 3
2007年 5月 JOURNAL OF NANJ ING UN IVERSITY OF TECHNOLOGY May 2007
纳米多孔配位聚合物的研究进展
朱敦如,周俊,杨捷,包魏魏,沈旋
(南京工业大学化学化工学院,江苏南京 210009)
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摘要: 纳米多孔材料可用作催化剂、气体储存材料和光电子器件,是目前新型多孔材料的研究热点之一. 借助自
组装技术,选择羧酸类、联吡啶类和吡啶羧酸类化合物作为桥联配体,可获得一维、二维2和三维的多孔配位聚合物.
简要综述了该类纳米多孔配位聚合物的设计原理、合成路线和应用前景,评价了其合成方法的优缺点. 由于其特殊
的结构和性质,纳米多孔配位聚合物将发展成为具有光、电、磁等性质的多功能材料.
关键词: 配位聚合物;多孔材料;结构;纳米材料
中图分类号: O611 6 文献标识码: A 文章编号: 1671 - 7627 (2007) 03 - 0103 - 08
Recen t developm en ts in nanoporous coord ina tion polym ers
ZHU Dun ru, ZHOU Jun, YANG J ie, BAO W ei wei, SHEN Xuan
(College of Chem istry and Chem ical Engineering, Nanjing University of Technology, Nanjing 210009, China)
Abstract:Nanoporous materials can be used for catalysis, gas storage, and op toelectronic devices, which is one of
extensively researched fields in novel porous materials. One dimensional (1D ) 、two dimensional (2D ) and three
dimensional ( 3D ) porous coordination polymers can be synthesized by the self assembly of metal ions and the
bridge linking ligands like carboxylates、pounds and isonictinic acids. The p rincip les of design, syn
thesis routes and potential app lications of the nanoporous coordination polymers have been briefly described, and
the advantages and disadvantages of the synthesis methods have been evaluated. Due to their special struct