文档介绍：Surface Modification of Polymers by Grafting
Yoshikimi Uyama1,Koichi Kato2, and Yoshito Ikada1*
* To whom correspondence should be addressed.
1 Research Center for Biomedical Engineering, Kyoto University, 53 Kawahara-cho, Shogoin,
Sakyo-ku, Kyoto 606, Japan. E-mail: ******@-
2 Department of Chemical Science and Engineering, Faculty of Engineering, Kobe University,
1–1 Rokkodai-cho, Nada-ku, Kobe 657, Japan
Recently a variety of technologies have been proposed for improving surface properties of poly-
mers. Among them is surface grafting of polymers. Although this is a rather new technology,
polymer surface grafting offers versatile means for providing existing polymers with new
functionalities such as hydrophilicity, adhesion, patibility, conductivity, anti-fogging,
anti-fouling, and lubrication. This review article describes various methods of grafting and
grafted surface characterizations. Medical and non-medical applications connected with this
polymer surface grafting are also presented referring to recent publications.
Keywords: Surface modification, Graft polymerization, Graft chain, Adhesion, Surface charac-
terization
1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
2 Creation of Grafted Surfaces . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Polymer Coupling Reactions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Graft Polymerization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Direct Chemical Modification . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Ozone . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
g-Rays . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Electron Beams . . . . . . . . . . . . .