文档介绍：TEMPLATE
POLYMERIZATION
Stefan Polowi' nski
Technical University of L'od'z
ChemTec Publishing
Copyright © 1997 by ChemTec Publishing
ISBN 1-895198-15-1
All rights reserved. No part of this publication may be reproduced, stored or transmitted in any form
or by any means without written permission of copyright owner. No responsibility is assumed by the
Author and the Publisher for any injury or/and damage to persons or properties as a matter of products
liability, negligence, use, or operation of any methods, product ideas, or instructions published or
suggested in this book.
Printed in Canada
ChemTec Publishing
38 Earswick Drive
Toronto-Scarborough
Ontario M1E 1C6
Canada
Canadian Cataloguing in Publication Data
Polowinski, Stefan
Template polymerization
Includes bibliographical references and index.
ISBN 1-895198-15-1
1. Polymerization. 2. Biochemical templates
I. Title
1997 547’.28 C96-900763-9
Table of Contents
1 Introduction 1
References 3
2 General Mechanism of Template Polymerization 5
Template Polycondensation 5
Chain Template Polymerization 9
Template Copolymerization 11
References 16
3 Templates and Orientation of Substrates on Template 19
References 25
4 Examples of Template Polymerization 27
Polyacids as Templates 27
Polyimines and Polyamines as Templates 34
Polybase Ionenes as Templates 35
Poly(ethylene oxide) and Poly(vinyl pyrrolidone) as
Templates 36
Poly(methyl methacrylate) as Template 44
Poly(vinylopyridines) as Templates 45
Other Templates 47
Multimonomers as Templates 49
Ring-opening Polymerization 52
References 56
5 Examples of Template Copolymerization 59
Template Copolycondensation 59
Ring Opening Template Copolymerization 59
Radical Template Copolymerization 60
Copolymerization with Participation of Multimonomers 60
Copolymerization of Two Different Multimonomers 68
Copolymerization