文档介绍：第 31 卷第 2 期玉林师范学院学报(自然科学)
2010 年 JOURNAL OF YULIN NORMAL UNIVERSITY (Natural Science)
硫酸高铈催化合成氯乙酸丙酯
□李家贵1,戴健榕2,陈渊3,朱万仁4
(1. 玉林师范学院化学与生物系副教授,广西玉林 537000)
(2. 玉林师范学院附属中学中学高级,广西玉林 537000)
(3. 玉林师范学院化学与生物系高级实验师,广西玉林 537000)
(4. 玉林师范学院化学与生物系教授,广西玉林 537000)
【摘要】以硫酸高铈催化氯乙酸与丙醇酯化反应合成了氯乙酸丙酯. 较适宜的反应条件为:氯
乙酸50mmol,n(氯乙酸)∶n(丙醇)=1∶,ω(催化剂)=%, mL,于95℃~110℃
反应2 h,%.
【关键词】硫酸高铈;催化合成;氯乙酸丙酯
【中图分类号】O62 【文献标识码】 A 【文章编号】1004-4671(2010)02-0032-04
化学研究
Catelyzed Synthesis of Propyl Chloroacetate by
Cerium Sulphate
LI Jia-gui1,DAI Jian-rong2,CHEN Yuang3,ZHU Wan-ren4
(1. Associate Professor, Dept. of Chemistry & Biology, Yulin Normal University,
Yulin, Guangxi 537000)
(2. Senior Teacher, The Middle School Attached to Yulin Nomal University,
Yulin, Guangxi 537000)
(3. Senior Lab Technician, Dept. of Chemistry & Biology, Yulin Normal University,
Yulin, Guangxi 537000)
(4. Professor, Dept. of Chemistry & Biology, Yulin Normal University, Yulin,
Guangxi 537000)
Abstract: Propyl chloroacetate was synthesized by the esterification of the chloroacetic
acid and propanol using cerium sulphate crystal as catalyst. The appropriate reaction
conditions at 95~110℃ for 2hs were as follows: The chloroacetic acid was 50mmol; molar
ratio of chloroacetic acid to propanol is 1:, ω(catalyst) was %; cyclohexa