文档介绍：第十章习题解答
习题 10-1
CH =CH CH CH=CH
(1) 2 2 < 3 2
(2) CH3CH=CHCH3 < CH2=CHCH=CH2
(3) CH=CH > CH=CH
(4) CH3CH=CHCH3 < H2CH3
CH3 CH3
习题 10-2
Br
(1) (2) ± CN
Br
(3) 若为 1mol HBr H3CHC C CH(CH3)2 + CHCH(CH3)2
Br Br
Br Br
若为 2mol HBr CH3CH2 C CH(CH3)2 + CH3 C CH2CH(CH3)2
Br Br
(4) CH3OCHCH3 (5) (CH3)3NCH2CH2Br (6) CF3CH2CHCl
Br Br
习题 10-3
(1) (2) (3) or
习题 10-4
NaOH H O CH CH CHCH
CH CH CH CH Br CH CH CH CH 2 3 2 3
(1) 3 2 2 2 3 2 2 +
∆ H OH
NaOH H O CH CH CHCH
(2) CH CH CH CH Br CH CH CH CH 2 3 2 3
3 2 2 2 3 2 2 +
∆ H OH
CH3CH2CHCH3 CH3CH2CHCH3
Na CH3CH2CH2CH2Br
ONa OCH2CH2CH2CH3
(1) NaNH2 (1) NaNH2
(3) HC CH HC C C C
(2) Br (2) Br
H H Br
+ CC
Br
(A)
Li Li CuI CuLi A
Br 2
习题 10-5
两个异构体,互为对映异构体。
HBr +
H CH H C H
H C CH 3 3
3 3 H3C Br Br CH3
习题 10-6
OH OH
+
(1) H2O/H + (主)
H H
OH OH
+
(2) H2O/H + (主)
H H
OH
OH
H H
OH
H O/H+
2 or
(3) more stable
HO
+
H2O/H or
more stable
习题 10-7
(CH CH ) CCH CH
(1) 3 2 2 2 3
Br
CH3 CH3
(2) CH3CH2C CHCH3 + CH3CH2C CHCH3
CH Br
Br 3
习题 10-8
Nu CH3 CH3 Nu
(1) CH CH CH CH CH CH (2) CH C CH C CH C(CH )
3 2 n 2 3 2 n 2 3 2
Ph Ph Ph CH3 CH3
Nu
(3) CH CH CH CH H
3 2 n 2 3
CH3 CH3
习题 10-9
Br Br
H C H
H H δδ H H 3
Br Br Br H3C H
CH + Br Br
H3C 3 H
H3C CH3 a H3C
b H C H
Br 3